A series of oxygen-bleached Norway spruce kraft pulps was analyzed by
the alkaline nitrobenzene oxidation and phenyl nucleus exchange techni
ques. It has been shown that the initial rapid oxygen delignification
was largely attributed to the degradation of those condensed units ori
ginated in the wood lignin. The diphenylmethane-type condensed structu
res formed during kraft pulping were fairly resistant to the oxidative
degradation, and its proportion in the residual lignin increased stea
dily with the bleaching process.