STUDY OF COMPLEX-FORMING PROCESSES BETWEEN IODINE AND CROWN-ETHERS IN2-PHASE SYSTEMS

Authors
LUCA C GHEORGHIU A CONSTANTINESCU T
Citation
C. Luca et al., STUDY OF COMPLEX-FORMING PROCESSES BETWEEN IODINE AND CROWN-ETHERS IN2-PHASE SYSTEMS, Revue Roumaine de Chimie, 39(3), 1994, pp. 297-305
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Revue Roumaine de Chimie → ACNP
ISSN journal
00353930
Volume
39
Issue
3
Year of publication
1994
Pages
297 - 305
Database
ISI
SICI code
0035-3930(1994)39:3<297:SOCPBI>2.0.ZU;2-W
Abstract
The study of complex-formation between iodine and crown ethers (CE) in two-phase systems (water containing I2 + KI and dichloroethane contai ning CE 12-C-4, 15-C-5, 18-C-6, B-15-C-5, DB-18-C-6, 4'-NO2-B-15-C-5) has led to the following conclusions: (i) charge-transfer complexes wh ich contain the l3(-) anion species are formed in the organic phase; ( ii) the combination ratios and equilibrium constants of these complexe s depend on the type of CE present in the organic phase.