A. Shukla et al., RELATIVISTIC MANY-BODY CALCULATION OF THE ELECTRIC-DIPOLE MOMENT OF ATOMIC RUBIDIUM DUE TO PARITY AND TIME-REVERSAL VIOLATION, Physical review. A, 50(2), 1994, pp. 1155-1171
In this paper fully ab initio calculations of the electric dipole mome
nt (EDM) of atomic rubidium due to two possible mechanisms-the intrins
ic electric dipole moment of the electron and the scalar-pseudoscalar
coupling between the electrons and the nucleons-are presented. The cal
culations were carried out using an approach which is a hybrid of the
diagrammatic many-body perturbation theory (MBPT) and the multiconfigu
ration Dirac-Fock method. These calculations, unlike any of the previo
us MBPT calculations for the rubidium atom, also take into account the
effects of electron pair correlations on the atomic EDM. Our results
demonstrate that these effects can make significant contributions to t
he EDM of alkali-metal atoms.