The evolution of K-L2,3L2,3 1D2 radiationless resonant Raman scatterin
g into Auger-electron emission was studied by tuning synchrotron radia
tion across the K edge of P in InP. The spectrum can be interpreted in
terms of a two-component model that involves excitation of a photoele
ctron (1) into a discrete excitonlike state and (2) into the continuum
; extra-atomic relaxation is taken into account. Auxiliary studies of
above-threshold Auger and photoelectron spectra arising from K photoio
nization were used to identify the dominantly atomic features of these
spectra.