SYNTHESES AND CRYSTAL-STRUCTURES OF 2 HETEROMETALLIC INCOMPLETE CUBANE-LIKE CLUSTERS - [(MOAG2S3C5H5NS)(PPH(3))(2)(S)]CENTER-DOT-CH2CL2 AND[(WAG2SE3C5H5NS)(PPH(3))(2)(SE)]CENTER-DOT-CH2CL2

Authors
WANG QM WU XT HUANG Q SHENG TL LIN P
Citation
Qm. Wang et al., SYNTHESES AND CRYSTAL-STRUCTURES OF 2 HETEROMETALLIC INCOMPLETE CUBANE-LIKE CLUSTERS - [(MOAG2S3C5H5NS)(PPH(3))(2)(S)]CENTER-DOT-CH2CL2 AND[(WAG2SE3C5H5NS)(PPH(3))(2)(SE)]CENTER-DOT-CH2CL2, Polyhedron, 16(9), 1997, pp. 1543-1548
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
9
Year of publication
1997
Pages
1543 - 1548
Database
ISI
SICI code
0277-5387(1997)16:9<1543:SACO2H>2.0.ZU;2-D
Abstract
Two incomplete cubane-like clusters, [{MoAg2S3C5H5NS}(PPh(3))(2)(S)]. CH2Cl2 (I) and [{WAg2 Se3C5H5NS}(PPh(3))(2)(Se)]. CH2Cl2 (II), were ob tained from the reaction of MoS4Ag2(PPh(3))(3) and WSe4 Ag-2(PPh(3))(3 ) with excess C5H5NS in CH2Cl2 solvent. The X-ray crystallography anal ysis shows that I and II have incomplete cubane-like structures, in wh ich the Mo(W) and Ag atoms are tetrahedrally coordinated. (C) 1997 Els evier Science Ltd.