Degenerate ground-state conjugated polymers exhibit large third-order
nonlinear optical susceptibilities, including substantial two-photon a
bsorption. With the use of a machine architecture suited to these mate
rial properties, ultrafast optical processors are possible. A four-wav
e mixing optical correlator was built with an air-stable, processable,
degenerate ground-state conjugated polymer, poly(1,6-heptadiester). T
he continuously updatable processor correlates two 5000-pixel images i
n less than 160 femtoseconds, achieving peak processing rates of 3 x 1
0(16) operations per second.