IMIDAZOLE DERIVATIVES .11. (C8H14N2)M(CO) 5 (M=MO, W) - TERMINAL COORDINATION OF AN OLEFIN IN PENTACARBONYL METAL-COMPLEXES

Authors
KUHN N BOHNEN H BLASER D BOESE R
Citation
N. Kuhn et al., IMIDAZOLE DERIVATIVES .11. (C8H14N2)M(CO) 5 (M=MO, W) - TERMINAL COORDINATION OF AN OLEFIN IN PENTACARBONYL METAL-COMPLEXES, Chemische Berichte, 127(8), 1994, pp. 1405-1407
Citations number
39
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
127
Issue
8
Year of publication
1994
Pages
1405 - 1407
Database
ISI
SICI code
0009-2940(1994)127:8<1405:ID.(5(>2.0.ZU;2-Q
Abstract
The 2-methylenimidazoline complexes (C8H14N2)M(CO)5 (M = Mo, W; 6) are obtained from M(CO)6 and 1,3,4,5-tetra-methyl-2-methyleneimidazoline (5). Spectroscopic data reveal the strong donor character of the ylidi c ligand in 6. The end-on coordination mode of the olefin is demonstra ted by an X-ray structure analysis of 6a.