The determination of the maximum permissible degree of colouration for
an electrochromic film in a particular device is technically importan
t for long-term reversible modulation and safe operation. Chronopatent
iometry combined with cyclic voltammetry have been used to examine the
degree of colouration for WO3 films on various conducting substrates
and electrolytes. The results revealed that an overreduced WO3 film wi
th high amount of intercalated ions will lose its reversibility, lower
ing its electrochromic performance.