DIMETHYL SULFATE-INDUCED NUCLEOPHILIC-SUBSTITUTION OF THE [BIS(1,2-DICARBOLLIDO)-3-COBALT(1-)]ATE ION - SYNTHESES, PROPERTIES AND STRUCTURES OF ITS 8,8'-MU-SULFATO, 8-PHENYL AND 8-DIOXANE DERIVATIVES

Authors
PLESEK J HERMANEK S FRANKEN A CISAROVA I NACHTIGAL C
Citation
J. Plesek et al., DIMETHYL SULFATE-INDUCED NUCLEOPHILIC-SUBSTITUTION OF THE [BIS(1,2-DICARBOLLIDO)-3-COBALT(1-)]ATE ION - SYNTHESES, PROPERTIES AND STRUCTURES OF ITS 8,8'-MU-SULFATO, 8-PHENYL AND 8-DIOXANE DERIVATIVES, Collection of Czechoslovak Chemical Communications, 62(1), 1997, pp. 47-56
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Collection of Czechoslovak Chemical Communications → ACNP
ISSN journal
00100765
Volume
62
Issue
1
Year of publication
1997
Pages
47 - 56
Database
ISI
SICI code
0010-0765(1997)62:1<47:DSNOT[>2.0.ZU;2-D
Abstract
Syntheses and structures of [8,8'-mu-(OSO2O)(1,2-C2B9H10)(2)-3-Co](-) and [(8-Ph-1,2-C2B9H10)-3-Co-(1',2'-C2B9H11](-) ions and of [(8-dioxan e-1,2-C2B9H10)-3-Co-(1',2'-C2B9H11)] zwitterion are described. All com pounds result on dimethyl sulfate induced nucleophilic B-substitution of the parent cobalta-carborane sandwich ion under acid catalysis. A g eneral mechanism is proposed. Constitutions of all compounds are infer red from the mass and multinuclear NMR spectroscopy and all structures are established by X-ray diffraction. Selected NMR and X-ray data are presented.