SYNTHESIS AND THERMOLYSIS OF TETRACOORDINATE 1,2-OXAPHOSPHETANES STABILIZED BY STERIC PROTECTION

Authors
KAWASHIMA T TAKAMI H OKAZAKI R
Citation
T. Kawashima et al., SYNTHESIS AND THERMOLYSIS OF TETRACOORDINATE 1,2-OXAPHOSPHETANES STABILIZED BY STERIC PROTECTION, Chemistry Letters, (8), 1994, pp. 1487-1490
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
8
Year of publication
1994
Pages
1487 - 1490
Database
ISI
SICI code
0366-7022(1994):8<1487:SATOT1>2.0.ZU;2-L
Abstract
The title compounds bearing a 2,4,6-triisopropylphenyl group stable in air at room temperature were synthesized in good yields by intramolec ular dehydration of the corresponding beta-hydroxy phosphinic acids. T hermolysis gave the corresponding olefin along with ring-opening produ cts. Selectivity of olefin formation depends on additives.