F. Mizutani et S. Yabuki, HIGHLY-SENSITIVE MEASUREMENT OF DIHYDROXYPHENOLS USING CARBON FELT ELECTRODE IMPREGNATED WITH FRUCTOSE DEHYDROGENASE-CONTAINING SOLUTION, Chemistry Letters, (8), 1994, pp. 1569-1572
A carbon felt electrode impregnated with a fructose dehydrogenase/fruc
tose-containing solution was used for measuring dihydroxyphenols (eg,
catechol and dopamine). Dihydroxyphenol molecules are oxidized on the
electrode but regenerated by the enzyme reaction. The consumption/rege
neration cycle for dihydroxyphenols resulted in an amplified electrode
response. Further, the measuring method could be free from the electr
ochemical interference by oxidizable species such as L-ascorbic acid.