We report results of a comparative study of three nonmetals related to
the 1-2-3 cuprate superconductors: fully oxygenated PrBa2Cu3Oy (PBCO)
, YBa2Cu2CoOy (YBCCO), and PrBa2Cu2CoOy (PBCCO). We measured the resis
tivity up to 300 K and the absolute thermopower (TEP) up to 400 K. The
temperature dependence of the resistivity follows the Mott variable-r
ange-hopping (VRH) law rho = rho0exp(T0/T)1/4 in PBCO up to approximat
ely 100 K and in the other two systems at least up to room temperature
. The results of the TEP measurements show that in YBCCO and in PBCCO
the VRH probably takes place via energy states lying mainly below the
chemical potential, while in PBCO this process utilizes states lying s
ymmetrically on both sides of the chemical potential. In PBCO the TEP
exhibits a cusp at low temperatures that is probably associated with t
he Neel point of the Pr sublattice. In PBCCO we found at low temperatu
res a sharp sign reversal of the TEP, from p type at high temperatures
to n type at low temperatures, which needs further investigation.