ONLINE RADIOISOTOPE XRF ANALYSIS OF COPPER, ARSENIC, AND SULFUR IN COPPER ELECTROLYTE PURIFICATION SOLUTIONS

The U.S. Bureau of Mines (USBM) and Weber State University (WSU) have developed an on-line analysis system for copper electrolytic solutions in a laboratory-scale decopperization electrolytic cell using a porta ble energy-dispersive X-ray fluorescence (XRF) unit. The portable XRF unit utilizes Fe-55 and Cm-244 radioactive isotope sources for sample analysis. Copper, sulfur, and arsenic were successfully analyzed direc tly in electrolytic purification solutions without any dilution or sam ple alteration. Interelement deconvolution was conducted to compensate for interferences resulting from matrix absorption of copper fluoresc ence by sulfur. The ubiquitous presence of sulfur in copper refining o perations necessitates sulfur correction in the analysis of copper by XRF. A unique flow-through sampling cell was engineered and constructe d for the portable XRF unit which allowed real-time analysis of a cont inuously pumped sample stream from the electrolytic cell.