The reduced electrical field strength is a key physical input to plasm
a chemistry and vibrational kinetics models of CO2 laser discharges. I
n this paper the different processes that influence the ionization equ
ilibrium are studied and a tractable model is constructed from which t
he self-sustaining electrical field in the positive column of a flowin
g CO2 laser mixture is derived. Apart from the charged particle losses
related to the turbulent flow, a number of plasma-chemical effects su
ch as CO2 dissociation and water contamination are included in the ana
lysis. The total negative-ion density is denoted as a critical quantit
y in explaining experimental reduced electrical field values.