P. Dutta et al., A LINEAR LEAST-SQUARES VARIATIONAL RECIPE FOR THE CALCULATION OF APPROXIMATE ENERGY EIGENSTATES, Chemical physics letters, 226(1-2), 1994, pp. 73-81
The efficacy of the energy-spread minimization technique for solving t
he energy-eigenvalue equation in a linear variational framework is ass
essed with a 3 x 3 matrix perturbation problem with backdoor intruders
, quartic anharmonic oscillator and the He-atom problems as prototypic
al examples. Both direct and indirect minimization schemes are conside
red and disadvantages of the latter pointed out. The relative merits a
nd demerits of the conventional, vis-a-vis stochastic minimization rou
tes are critically analyzed in the present context.