We show that transmission-mode perpendicular incidence ellipsometry, w
hich yields the trivial values PSI = 45-degrees, DELTA = 0 for an isot
ropic thin film, can be used to provide useful data during the vacuum
deposition of anisotropic coatings. Thus the number of quarter-wave fi
lm thicknesses necessary for a quarter-wave retardation plate can be d
etermined simply by counting interference modulations on a DELTA versu
s PSI graph, and the material property DELTAn, the difference between
the slow and fast axis refractive indices, is available from the gradi
ent of a smoothed DELTA versus thickness graph. The influences of diff
erential absorption, differential refractive index inhomogeneity, and
instrumental errors on the ellipsometric parameters are discussed.