Mc. Thoms, A FREEZE-SAMPLING TECHNIQUE FOR THE COLLECTION OF ACTIVE STREAM SEDIMENTS USED IN MINERAL EXPLORATION AND ENVIRONMENTAL-STUDIES, Journal of geochemical exploration, 51(2), 1994, pp. 131-141
This paper compares freeze- and grab-sampling techniques for the colle
ction of active stream sediments. statistical analysis indicates a sig
nificant difference (p < 0.01) between the two techniques for all of t
he 10 oxides and 21 minor elements analysed. The percent weight of oxi
de and elemental concentrations obtained at over 122 sampling location
s indicate that.freeze-sampling collects representative sediment sampl
es. Fifty percent fewer freeze-samples are required per site in order
to obtain representative estimates of the percentage oxide and element
concentration in the sediment. In contrast, grab-sampling introduces
a bias in the textural composition of the minus 125 mum (120 mesh or 3
phi) fraction, the sediment interval used for routine geochemical anal
ysis, because of wash out and elutriation of finer fractions. The free
ze-sampling technique is recommended for mineral exploration and basel
ine environmental studies.