GLYCIDYL METHACRYLATE AND N-VINYLPYRROLIDINONE COPOLYMERS - SYNTHESISAND NUCLEAR-MAGNETIC-RESONANCE CHARACTERIZATION

Authors
HUNTER TC PRICE GJ
Citation
Tc. Hunter et Gj. Price, GLYCIDYL METHACRYLATE AND N-VINYLPYRROLIDINONE COPOLYMERS - SYNTHESISAND NUCLEAR-MAGNETIC-RESONANCE CHARACTERIZATION, Polymer, 35(16), 1994, pp. 3530-3534
Citations number
21
Categorie Soggetti
Polymer Sciences
Journal title
Polymer → ACNP
ISSN journal
00323861
Volume
35
Issue
16
Year of publication
1994
Pages
3530 - 3534
Database
ISI
SICI code
0032-3861(1994)35:16<3530:GMANC->2.0.ZU;2-2
Abstract
Poly(glycidyl methacrylate) and water-soluble copolymers of glycidyl m ethacrylate with N-vinylpyrrolidinone were prepared by free-radical-in itiated solution polymerization in chloroform. Polymer microstructure was investigated by high-field H-1 and C-13 nuclear magnetic resonance (n.m.r.), H-1 decoupled C-13 n.m.r., H-1-C-13 correlation n.m.r. and 135 DEPT (distortionless enhancement by polarization transfer) n.m.r. The combined use of these techniques allowed unequivocal C-13 and H-1 n.m.r. assignments of carbons and protons to be established. Copolymer composition was thus determined from H-1 n.m.r.