P. Clechet et al., LUBRICATION OF SILICON MICROMECHANISMS BY CHEMICAL GRAFTING OF LONG-CHAIN MOLECULES, Sensors and actuators. A, Physical, 44(1), 1994, pp. 77-81
A method involving the grafting of long-chain molecules on hydroxylate
d ceramic surfaces like silica is proposed to improve lubrication in m
icroactuators. Preliminary experiments show that one monolayer of octa
decyl and docosyl silane molecules does improve the sliding properties
of silica. The friction tests are performed on a reciprocating tribom
eter, in a sphere and plane geometry with a contact pressure of 340 MP
a. The friction-reduction effect is clearly evidenced, the value of th
e friction coefficient decreasing from 0.6-0.7 to nearly 0.1 in the pr
esence of the grafted molecule layer. The lifetime of the effect is es
timated as one hundred cycles. In a prospective view, these results ar
e extended to contacts in micromechanisms.