The interaction of sol-gel derived glass/organic polymer composite gel
monoliths, containing a calcium salt, with an ambient solution of sim
ulated body fluid was investigated. These gels were aged, wetted, plac
ed in simulated body fluid, and then observed with a scanning electron
microscope. The chemical compositions of the sample and the apatite w
ere determined by energy dispersive X-ray analysis. A calcium phosphat
e apatite layer was clearly observed after 7 days, as was an intermedi
ate layer which included not only calcium and phosphate in its composi
tion but also silicon. Calcium and phosphate were also observed to be
present in the outer layer of the sample, presumably having precipitat
ed on the external surfaces of the pores in the SiO2 network.