DEPENDENCE OF ELECTROCHEMICAL-BEHAVIOR OF POLYETHYLENEIMINE FILMS ON THEIR CROSS-LINKING DEGREE AND THE SUPPORTING-ELECTROLYTE SOLUTION PH

Authors
KHALDUN M MAKSIMOV YM TARASEVICH BN PODLOVCHENKO BI
Citation
M. Khaldun et al., DEPENDENCE OF ELECTROCHEMICAL-BEHAVIOR OF POLYETHYLENEIMINE FILMS ON THEIR CROSS-LINKING DEGREE AND THE SUPPORTING-ELECTROLYTE SOLUTION PH, Russian journal of electrochemistry, 30(7), 1994, pp. 799-804
Citations number
19
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
30
Issue
7
Year of publication
1994
Pages
799 - 804
Database
ISI
SICI code
1023-1935(1994)30:7<799:DOEOPF>2.0.ZU;2-B
Abstract
A study of the electrochemical characteristics of glassy carbon electr odes modified by polyethyleneimine films with different degrees of cro ss-linking when the acidity of the supporting electrolyte changes is c arried out. It is shown that as the degree of cross-linking increases, the stability of the films and the formal coefficient of the charge d iffusion also increase. An increase in the solution pH leads to a decr ease in the number of redox anions taking part in the electrode proces s.