POLYPARAPHENYLENE FILM ELECTRODEPOSITION ON METAL BACKINGS OF DIFFERENT NATURES AND MORPHOLOGY

Citation
Ey. Pisarevskaya et al., POLYPARAPHENYLENE FILM ELECTRODEPOSITION ON METAL BACKINGS OF DIFFERENT NATURES AND MORPHOLOGY, Russian journal of electrochemistry, 30(7), 1994, pp. 831-840
Citations number
16
Categorie Soggetti
Electrochemistry
ISSN journal
10231935
Volume
30
Issue
7
Year of publication
1994
Pages
831 - 840
Database
ISI
SICI code
1023-1935(1994)30:7<831:PFEOMB>2.0.ZU;2-T
Abstract
Electrosynthesis of an electroconductive polymer, i.e., polyparaphenyl ene on metal backings with different morphology, is studied. It is sho wn that, in synthesizing polyparaphenylene from a benzene emulsion in strong sulfuric acid, in addition to noble metals, base metals and cer tain alloys can be used as electrodes. It is proved experimentally tha t differences in the morphology of electrode materials, found by apply ing the nonstationary electrolysis method, lead to the differences in both the polymer growth rate and the morphology of the obtained polypa raphenylene films.