ELECTROKINETIC EFFECT IN CAPILLARY SYSTEMS WITH A NONUNIFORM SURFACE-CHARGE DENSITY

Citation
Vm. Agafonov et al., ELECTROKINETIC EFFECT IN CAPILLARY SYSTEMS WITH A NONUNIFORM SURFACE-CHARGE DENSITY, Russian journal of electrochemistry, 30(7), 1994, pp. 846-849
Citations number
7
Categorie Soggetti
Electrochemistry
ISSN journal
10231935
Volume
30
Issue
7
Year of publication
1994
Pages
846 - 849
Database
ISI
SICI code
1023-1935(1994)30:7<846:EEICSW>2.0.ZU;2-Z
Abstract
A study has been undertaken to see how a nonuniform surface charge dis tribution affects the pattern of electrolyte flow in a flat capillary greater than the Debye screening length thick in the presence of a con stant pressure drop between its ends. It is shown that the corrections applied to the kinetic coefficients take a minus sign and that for re al system parameters they are 5 - 10% of the values calculated for cap illaries with uniformly charged walls.