CU AND ZN ORDERING IN AURICHALCITE

The advantages of X-ray absorption spectroscopy have been utilized to assess the Cu and Zn ordering in aurichalcite, (Cu5-xZnx)(OH)(6)(CO3)( 2). We have examined one hydrozincite sample and three aurichalcite sa mples in which the Cu:Zn ratios are in the range 1:3 to 2:3. Copper 2p XAS confirms that there is no monovalent copper in aurichalcite and t hat in each sample the copper might be distributed across more than on e metal site. EXAFS, at the Cu and Zn K-edges, shows that the copper a toms preferentially enter the Jahn-Teller elongated, octahedral (M2) a nd trigonal bipyramidal (M4) sites, with the zinc atoms entering the m ore regular octahedral (M1) and tetrahedral (M3) site. Substantial sol id solution towards the zinc rich region is facilitated by the substit ution of copper by zinc on the M2 and M4 sites. This information, not easily obtained by X-ray diffraction, substantially enhances the under standing of the structure of aurichalcite.