A MILD AND CONVENIENT SYNTHESIS OF FUNCTIONALIZED METHYL TRIFLONES AND VINYL TRIFLONES

Authors
MAHADEVAN A FUCHS PL
Citation
A. Mahadevan et Pl. Fuchs, A MILD AND CONVENIENT SYNTHESIS OF FUNCTIONALIZED METHYL TRIFLONES AND VINYL TRIFLONES, Tetrahedron letters, 35(33), 1994, pp. 6025-6028
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
33
Year of publication
1994
Pages
6025 - 6028
Database
ISI
SICI code
0040-4039(1994)35:33<6025:AMACSO>2.0.ZU;2-#
Abstract
A general route for the synthesis of methyl triflone derivatives utili zing triflic anhydride is described. Stereoselective synthesis of E-vi nyl and dienyl triflones has been accomplished by the Peterson olefina tion reaction of alpha-silyl triflone anions.