ARENETHIOLATOCOPPER(I) COMPLEXES AS HOMOGENEOUS CATALYSTS FOR MICHAELADDITION-REACTIONS

Authors
VANKLAVEREN M LAMBERT F EIJKELKAMP DJFM GROVE DM VANKOTEN G
Citation
M. Vanklaveren et al., ARENETHIOLATOCOPPER(I) COMPLEXES AS HOMOGENEOUS CATALYSTS FOR MICHAELADDITION-REACTIONS, Tetrahedron letters, 35(33), 1994, pp. 6135-6138
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
33
Year of publication
1994
Pages
6135 - 6138
Database
ISI
SICI code
0040-4039(1994)35:33<6135:ACAHCF>2.0.ZU;2-G
Abstract
Arenethiolatocopper(I) complexes are shown to be efficient homogeneous catalysts in Michael addition reactions of several Grignard reagents to acyclic enones; the addition products are formed with excellent che moselectivity (>99%) and good enantioselectivity (76% e.e.).