Corrugated mats of palygorskite occurring in regolith overlying a fiss
ured limestone were examined by X-ray diffraction, infrared spectrosco
py. and electron optical techniques after heating at 50-degrees-C inte
rvals to 700-degrees-C. Palygorskite 'anhydride' formed at 400-degrees
-C and sillimanite formed at 500-degrees-C. The palygorskite is believ
ed to have formed in joints in limestone of Upper Oligocene age (Duntr
oonian) prior to uplift and subsequent weathering. It is highly crysta
lline, and appears not to have altered or weathered since precipitatio
n.