A NEW, SIMPLE, EFFICIENT ELECTROSYNTHESIS OF FUNCTIONALIZED BENZYLIC ZINC SPECIES AND THEIR REACTIVITY TOWARD AROMATIC-ALDEHYDES

Authors
GOSMINI C ROLLIN Y GEBEHENNE C LOJOU E RATOVELOMANANA V PERICHON J
Citation
C. Gosmini et al., A NEW, SIMPLE, EFFICIENT ELECTROSYNTHESIS OF FUNCTIONALIZED BENZYLIC ZINC SPECIES AND THEIR REACTIVITY TOWARD AROMATIC-ALDEHYDES, Tetrahedron letters, 35(31), 1994, pp. 5637-5640
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
31
Year of publication
1994
Pages
5637 - 5640
Database
ISI
SICI code
0040-4039(1994)35:31<5637:ANSEEO>2.0.ZU;2-L
Abstract
Various stable substituted benzylic zincs are formed in acetonitrile u pon reaction of the bromide derivatives, in good yields, using a catal ytic electrogenerated zinc species associated with massive zinc. In th e presence of chloronimethylsilane, these organozincs react instantane ously with functionalized aromatic aldehydes.