COBALT-CATALYZED REGIOSELECTIVE ALLYLATION OF 1,3-DICARBONYL COMPOUNDS

Authors
MAIKAP GC REDDY MM MUKHOPADHYAY M BHATIA B IQBAL J
Citation
Gc. Maikap et al., COBALT-CATALYZED REGIOSELECTIVE ALLYLATION OF 1,3-DICARBONYL COMPOUNDS, Tetrahedron, 50(30), 1994, pp. 9145-9156
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
30
Year of publication
1994
Pages
9145 - 9156
Database
ISI
SICI code
0040-4020(1994)50:30<9145:CRAO1C>2.0.ZU;2-D
Abstract
Catalytic amount of Cobalt(II) chloride in 1,2-dichloroethane promotes the allylation of 1,3-dicarbonyl compounds with allyl acetates in hig h yields. The allylation of pentane-2,4-dione is highly regioselective as compared with methylacetoacetate and ethyl 2-oxocyclopentanecarbox ylate.