A NEW NMR METHOD FOR MEASURING THE LOCAL CORRELATION TIMES OF MOLECULES IN THE LIQUID-STATE

Authors
DESVAUX H GOLDMAN M
Citation
H. Desvaux et M. Goldman, A NEW NMR METHOD FOR MEASURING THE LOCAL CORRELATION TIMES OF MOLECULES IN THE LIQUID-STATE, Journal de chimie physique et de physico-chimie biologique, 91(6), 1994, pp. 653-659
Citations number
10
Categorie Soggetti
Biology,"Chemistry Physical
Journal title
Journal de chimie physique et de physico-chimie biologique → ACNP
Volume
91
Issue
6
Year of publication
1994
Pages
653 - 659
Database
ISI
SICI code
Abstract
The steady-state magnetizations of homonuclear spins experiencing a st rong off-resonance irradiation are aligned with the effective field. T heir amplitude is a function of the correlation time and of the angle between the static field and the effective field in the rotating frame . By varying the latter, one can determine the effective local correla tion time or test large departure from isotropic Brownian rotation. Ex perimental illustrations are given.