R. Boscaino et al., ANOMALOUS TIME DECAY OF TRANSIENT NUTATIONS IN S=1 2 SPIN SYSTEMS/, Journal de chimie physique et de physico-chimie biologique, 91(6), 1994, pp. 664-668
The damping of the transient nutations has been investigated experimen
tally at microwave frequency in two-level spin systems (E' centers in
silica and [AlO4]degrees in quartz). Transient nutation signals decay
exponentially but with a rate much faster than expected from a phenome
nological Bloch model. We find a linear dependence of the damping rate
on the Rabi frequency. We have not yet found a satisfactory explanati
on of this anomalous behavior.