PALLADIUM-CATALYZED HYDROGENATION OF ALPHA,BETA-UNSATURATED SULFONES AND PHOSPHONATES

Authors
CHO IS ALPER H
Citation
Is. Cho et H. Alper, PALLADIUM-CATALYZED HYDROGENATION OF ALPHA,BETA-UNSATURATED SULFONES AND PHOSPHONATES, Journal of organic chemistry, 59(15), 1994, pp. 4027-4028
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
59
Issue
15
Year of publication
1994
Pages
4027 - 4028
Database
ISI
SICI code
0022-3263(1994)59:15<4027:PHOASA>2.0.ZU;2-H
Abstract
The binuclear palladium complex, [(Bu(2)(t)PH)-PdPBu(2)(t)](2), when t reated with oxygen, catalyzes the hydrogenation of the double bond of alpha,beta-unsaturated sulfones and phosphonates in THF at room temper ature and 1 atm of hydrogen pressure. Saturated sulfones and phosphona tes were isolated in 49-93% yields.