SUBSTITUTION PRODUCTS OF 4,4,6,6-TETRACHL OTRIPHOSPHAZENE-2-SPIRO-3'-CYCLODI(PHOSPHADIAZANE)

Authors
DIEFENBACH U STORMBURG B ENGELHARDT U
Citation
U. Diefenbach et al., SUBSTITUTION PRODUCTS OF 4,4,6,6-TETRACHL OTRIPHOSPHAZENE-2-SPIRO-3'-CYCLODI(PHOSPHADIAZANE), Zeitschrift fur anorganische und allgemeine Chemie, 620(8), 1994, pp. 1434-1438
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
8
Year of publication
1994
Pages
1434 - 1438
Database
ISI
SICI code
0044-2313(1994)620:8<1434:SPO4O>2.0.ZU;2-D
Abstract
Reactions of the spiro compound otrophosphazene-2-spiro-3'-cyclodi(pho sphadiazane) Cl4N3P3(NH-NH)2P(S)OC6H5 with an excess of ammonia, cyclo propylamine, aziridine, and sodium phenolate were investigated. Fully or partially substitution of the chlorine atoms occurs. The reaction w ith two equivalents of the aziridine yields a mixture of isomers which consists of two geminal and two vicinal disubstituted products. The c onstitutions of the substituted compounds were confirmed by IR, NMR, M S and elemental analyses.