KINETIC INVESTIGATION OF THE OH-K AND 390-K(CH3BR REACTION BETWEEN 248)

Citation
A. Chichinin et al., KINETIC INVESTIGATION OF THE OH-K AND 390-K(CH3BR REACTION BETWEEN 248), Journal of atmospheric chemistry, 18(3), 1994, pp. 239-245
Citations number
14
Categorie Soggetti
Metereology & Atmospheric Sciences
ISSN journal
01677764
Volume
18
Issue
3
Year of publication
1994
Pages
239 - 245
Database
ISI
SICI code
0167-7764(1994)18:3<239:KIOTOA>2.0.ZU;2-X
Abstract
The rate parameters for the reaction of the OH radical with CH3Br have been measured using the discharge flow-electron paramagnetic resonanc e method. The result is k1 = (1.86+/-0.48) x 10(-12) exp[-(1230+/-150) /T] cm3 molecule-1 s-1. This value is compared to earlier data and is found to be in excellent agreement with the most recent results, which greatly increases the accuracy of the ozone depletion potential of CH 3Br which can be derived from these kinetic data.