Jh. Bulloch et Jj. Hickey, REVERSE TEMPER EMBRITTLEMENT OF TURBINE BOLTS DURING AN OUTAGE, Theoretical and applied fracture mechanics, 20(2), 1994, pp. 141-147
This paper describes a detailed examination which could be conducted d
uring a planned outage. It is concerned with assessing reverse temper
embrittlement of CrMoV steel turbine bolts after 120 000 h of service.
A small section of material was removed from a non-critical location
of all the 92 IP and HP bolts. From this section, the chemical composi
tion, average hardness and average prior austenite grain size were mea
sured. The toughness of the bolts was measured by Charpy impact testin
g and/or Auger electron spectroscopy. From the various parameters inve
stigated, it was established that grain size and phosphorus level were
the only factors which consistently identified whether a bolt was emb
rittled or non-embrittled. Indeed, at a phosphorus level of 0.01%, bol
ts with grain sizes less than 20 mum were not embrittled while those w
ith larger grain sizes suffered reverse temper embrittlement during se
rvice. An embrittlement estimative diagram was established by plotting
grain size versus phosphorus level (%P). This portrayed two distinct
regimes, an embrittled and non-embrittled regime which were separated
by a critical embrittled-non-embrittled interface which could be descr
ibed by d x (%P) = 0.18 where d is the grain size in mum. Such an embr
ittlement estimate diagram represent a cogent and practical route in t
he identification of in-service embrittled bolts.