SPECIFIC-HEATS OF DIPOLAR FLUIDS .1. PERTURBATION THEORETICAL RESULTS

Authors
SZALAI I LUKACS T LISZI J
Citation
I. Szalai et al., SPECIFIC-HEATS OF DIPOLAR FLUIDS .1. PERTURBATION THEORETICAL RESULTS, Zeitschrift für physikalische Chemie, 186, 1994, pp. 77-90
Citations number
20
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Zeitschrift für physikalische Chemie → ACNP
ISSN journal
09429352
Volume
186
Year of publication
1994
Part
1
Pages
77 - 90
Database
ISI
SICI code
0942-9352(1994)186:<77:SODF.P>2.0.ZU;2-C
Abstract
Isochoric, isobaric and saturation heat capacities of polarizable, dip olar hard-sphere fluids with variable polarizability were calculated a long with - and in the vicinity of - the vapour-liquid coexistence cur ve. As prerequisites of the calculation, orthobaric densities, vapour pressures and heats of vaporization were also calculated. The studied heat capacities show realistic behaviour in the vicinity of the phase- transition, and seem to be suitable for the description of real fluids .