INTERACTION OF ADSORBED CARBON-MONOXIDE WITH SURFACE HYDROXYL-GROUPS OF YTTRIUM, ERBIUM, AND HOLMIUM OXIDES

Authors
IVLIEVA RR ZUBKOV SA BOROVKOV VY KAZANSKII VB
Citation
Rr. Ivlieva et al., INTERACTION OF ADSORBED CARBON-MONOXIDE WITH SURFACE HYDROXYL-GROUPS OF YTTRIUM, ERBIUM, AND HOLMIUM OXIDES, Kinetics and catalysis, 35(3), 1994, pp. 382-387
Citations number
16
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
35
Issue
3
Year of publication
1994
Pages
382 - 387
Database
ISI
SICI code
0023-1584(1994)35:3<382:IOACWS>2.0.ZU;2-4
Abstract
The structure of oxygen-containing organic compounds formed at the sur face of yttrium, erbium, and holmium oxides upon interaction of CO wit h hydroxyl groups is studied by diffuse-reflectance IR spectroscopy. I t is shown that these species represent formate (HCO2-), formyl (HCO-) , and, perhaps, dioxymethylene groups (H2CO22-).