STYRENE ALKYLATION WITH METHANOL ON PENTASILS - CORRELATION OF ACIDICAND CATALYTIC PROPERTIES

Authors
PONOMAREVA OA KOVALEVA EB MOSKOVSKAYA IF ROMANOVSKII BV
Citation
Oa. Ponomareva et al., STYRENE ALKYLATION WITH METHANOL ON PENTASILS - CORRELATION OF ACIDICAND CATALYTIC PROPERTIES, Kinetics and catalysis, 35(3), 1994, pp. 411-415
Citations number
12
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
35
Issue
3
Year of publication
1994
Pages
411 - 415
Database
ISI
SICI code
0023-1584(1994)35:3<411:SAWMOP>2.0.ZU;2-M
Abstract
The total number of acid centers and their distribution according to t he strength in pentasil type zeolites both in the H-form and in the fo rm modified with phosphorus, magnesium, water vapor, tetraethoxysilane , and coke are determined by the method of temperature-programmed deso rption of ammonia. Using the method of regional rates, a correlation b etween the pentasil activity in styrene methylation and acidity is der ived. The acid-strength regions governing each pathway of the process of styrene methylation are found.