Gs. Was et al., CORROSION AND MECHANICAL-BEHAVIOR OF ION-IMPLANTED BEARING STEELS FORIMPROVED FRETTING BEHAVIOR, Surface & coatings technology, 66(1-3), 1994, pp. 446-452
Ion implantation of AISI 52100 and 1070 steels was conducted in order
to improve the corrosion, wear and ultimately the fretting behavior of
the steels. Implantations consisted of 1 X 10(17) Ta+ cm-2, 3 x 10(17
) Ti+ cm-2+1.5 x 10(17) C+ cm-2, and 3.1 x 10(17) Ti+ cm-2 + 1.55 x 10
(17) N2+ cm-2. All implantations were successful in improving the corr
osion resistance. On average, the peak anodic current was reduced by o
ver 300 mV, the passivation potential was reduced, and the pitting pot
ential was increased by over 1000 mV in 0.01 M NaCl. Ti + C and Ti + N
implantations increased the load-carrying capacity in lubricated scuf
fing tests by 60% and 40% respectively. Ta produced no improvement in
scuffing resistance. Ti + N implantation increased the hardness by 25%
over the unimplanted steel and both Ti + C and Ta implantation reduce
d the surface hardness. Fretting wear was reduced only slightly in the
Ta implanted sample and increased in both the Ti + C and Ti + N impla
nted samples with the latter showing 4-5 times the weight loss as the
unimplanted sample. The correlation between fretting and hardness supp
orts a mechanism in which the hard surface layer breaks into fine part
icles which act as an abrasive under the intense load of the balls.