A TETRANUCLEAR NEODYMIUM CAGE WHICH TIGHTLY BINDS SODIUM-CARBONATE MOLECULES

Authors
DEACON GB FENG TC HOCKLESS DCR JUNK PC SKELTON BW WHITE AH
Citation
Gb. Deacon et al., A TETRANUCLEAR NEODYMIUM CAGE WHICH TIGHTLY BINDS SODIUM-CARBONATE MOLECULES, Chemical communications, (4), 1997, pp. 341-342
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
4
Year of publication
1997
Pages
341 - 342
Database
ISI
SICI code
1359-7345(1997):4<341:ATNCWT>2.0.ZU;2-#
Abstract
The complexes [Na(2)Nd(4)L(4)(CO3)L'(4)] [H(3)L = (o-HOC6H4CH = NCH2)( 2)CHOH, L' = tetrahydrofuran or L'(2) = 1,2-dimethoxyethane] have nove l cage structures in which Nd4O12N8 bowl-shaped frameworks of Nd(4)L(4 ) molecules entrap solvated Na2CO3 molecules within the cavity of the bowl.