The microstructure and properties of two epoxy-resin systems which hav
e been modified with varying amounts of a thermoplastic to improve the
toughness of the thermosetting epoxy polymers, have been studied. The
curing agent was 4,4'-diaminodiphenylsulphone and the thermoplastic w
as a reactively terminated poly(ether sulphone) copolymer. Different m
icrostructures were found to occur as the concentration of the thermop
lastic component was steadily increased. In particular, the relationsh
ips between the microstructures and values of stress-intensity factor,
K(Ic), and fracture energy, G(Ic) were explored.