TEMPLATE SYNTHESIS OF [CR(EN)(3)][TE-6] - A NOVEL POLYTELLURIDE WITH A FRAMEWORK STRUCTURE, WHOSE CAVITIES ARE FILLED WITH A [CR(EN)(3)](3+) TEMPLATE

Authors
REISNER C TREMEL W
Citation
C. Reisner et W. Tremel, TEMPLATE SYNTHESIS OF [CR(EN)(3)][TE-6] - A NOVEL POLYTELLURIDE WITH A FRAMEWORK STRUCTURE, WHOSE CAVITIES ARE FILLED WITH A [CR(EN)(3)](3+) TEMPLATE, Chemical communications, (4), 1997, pp. 387-388
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
4
Year of publication
1997
Pages
387 - 388
Database
ISI
SICI code
1359-7345(1997):4<387:TSO[-A>2.0.ZU;2-G
Abstract
[Cr(en)(3)][Te-6] (en = ethylenediamine) is obtained by a template syn thesis under solvothermal conditions from Cr(CO)(6) and BaTe4; its cry stal structure contains a polymeric Te-6(3-) framework whose pores con tain the Cr(en)(3)(3+) template; [Cr(en)(3)][Te-6] is the first chalco genide with a porous three-dimensional framework structure.