Mq. Huang et al., MAGNETISM OF ALPHA'-FEN ALLOYS AND ALPHA''(FE16N2)FE NITRIDES, Journal of magnetism and magnetic materials, 135(2), 1994, pp. 226-230
The alpha'-FeN phase was prepared by treating Fe powder with NH3/H2 ga
s mixtures at a temperature of approximately 665-degrees-C followed by
a quench to cryogenic temperatures. Conversion of alpha to alpha' to
an extent exceeding 85% has been achieved. Alpha''-FeN is produced by
treatment of alpha' for approximately 1 to 2 h at 120-150-degrees-C. B
(sat) values obtained for alpha'- and alpha''-FeN are 23.5 and 26.6 kG
, respectively. The latter corresponds to 2.94mu(B)/Fe atom, a 34% enh
ancement over that of alpha-Fe.