PREPARATION OF 2,3-ANHYDROALLOPYRANOSIDES FUNCTIONALIZED IN THE 6-POSITION

Citation
F. Ponten et G. Magnusson, PREPARATION OF 2,3-ANHYDROALLOPYRANOSIDES FUNCTIONALIZED IN THE 6-POSITION, Acta chemica Scandinavica, 48(7), 1994, pp. 566-569
Citations number
10
Categorie Soggetti
Chemistry,Biology
Journal title
ISSN journal
0904213X
Volume
48
Issue
7
Year of publication
1994
Pages
566 - 569
Database
ISI
SICI code
0904-213X(1994)48:7<566:PO2FIT>2.0.ZU;2-U
Abstract
Treatment of methyl 2,3-anhydro-6-bromo-6-deoxy-alpha-D-allopyranoside with sodium phenylsulfinate, decanethiol, and 2-furylmethanethiol gav e sugar epoxides carrying sulfone or sulfide functionalities in the 6- position. Oxidation of the sulfides gave the corresponding sulfones.