High-resolution transmission electron microscopy (TEM) shows that MgO
films, grown on (001) GaAs by magnetron sputtering, are single crystal
with a cube-on-cube relationship with the substrate, even though they
are separated from the substrate by an amorphous interlayer. Scanning
TEM-energy dispersive x-ray and scanning TEM-electron energy loss spe
ctroscopy analysis of the interlayer shows that it consists of the nat
ive oxide of GaAs as well as nanocrystalline MgO. It is proposed that
epitaxial MgO nucleated at pin holes produced by volatilization of the
native oxide.