We have fabricated strained SixGe1-x/SiyGe1-y multiple quantum wells o
n Ge(100) substrates an measured the photoluminescence (PL) spectra, o
bserving band-edge emission from the SiGe alloy layers. The emission i
s due to the recombination of both bound excitons and free excitons in
the quantum wells. From the positions of the observed PL lines, we ha
ve evaluated the band-gap energies of the strained SiGe alloy layers,
and found them to be smaller than those of bulk SiGe alloys. The band-
gap energy increases with the Si content of the alloy, reaching a maxi
mum at about 15% Si, and subsequently decreases. These results agree w
ell with the theoretical calculations for strained layers, and suggest
a type II band alignment in some cases for SixGe1-x/SiyGe1-y heterost
ructures on Ge(100).