GENERATION OF ALPHA-ALKYLTHIO RADICALS BY PHOTOINDUCED ONE-ELECTRON OXIDATION OF ALPHA-STANNYL SULFIDES AND THEIR USE FOR CARBON-CARBON BOND FORMATION

Authors
IKENO T HARADA M ARAI N NARASAKA K
Citation
T. Ikeno et al., GENERATION OF ALPHA-ALKYLTHIO RADICALS BY PHOTOINDUCED ONE-ELECTRON OXIDATION OF ALPHA-STANNYL SULFIDES AND THEIR USE FOR CARBON-CARBON BOND FORMATION, Chemistry Letters, (2), 1997, pp. 169-170
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
2
Year of publication
1997
Pages
169 - 170
Database
ISI
SICI code
0366-7022(1997):2<169:GOARBP>2.0.ZU;2-K
Abstract
Cation radicals, generated from alpha-stannyl sulfides by the photoind uced single electron transfer, cleave into alpha-alkylthio radical int ermediates with the elimination of the stannyl group. The alpha-alkylt hio radicals thus formed are utilized for carbon-carbon bond forming r eactions.