Rh. Hellingwerf, REGIONAL AND LOCAL HYDROTHERMAL ALTERATION OF PROTEROZOIC METAVOLCANIC FOOTWALL ROCKS OF THE ZINKGRUVAN ZN-PB-AG ORE DEPOSIT, CENTRAL SWEDEN, Neues Jahrbuch fur Mineralogie Monatshefte, (11), 1997, pp. 491-518
The Zinkgruvan Zn-Pb-Ag deposit in Central Sweden is a Proterozoic str
atiform blanket-like ore body, hosted by a series of chemical-clastic
metatuffites, calc-silicate rocks, metacherts and marbles. This series
is underlain by a pile of felsic to intermediate metavolcanic rocks,
and covered by a sequence of quartz- feldspar- biotite sediments. The
metavolcanic footwall rocks have been affected by a number of hydrothe
rmal alterations: 1) regional sub-seafloor, low temperature K-feldspar
alteration in the upper parts of the volcanic column, overprinted by
higher temperature albitization in the lower parts; 2) local scale bor
on alteration (tourmalinization) in the footwall rocks and sedimentary
-exhalative sequences with mm-thick tourmalinites within and dm-thick
tourmalinites away from the main ore zone; 3) local scale silicificati
on overprinting the K- and Na-altered volcanites in restricted zones,
occasionally accompanying tourmalinization; 4) local scale ferromagnes
ian alteration (''magnesium metasomatism'') in semi-conformable zones
below a minor sulphide deposit; 5) local scale, infiltration and vein
controlled calc-silicate alteration, clearly overprinting older silici
fication; and 6) local scale phyllic alteration of various types and a
ges. Field observations and microscopic studies indicate that tourmali
nization, silicification and ferromagnesian alteration occurred prior
to regional compressional deformation. Most of the tourmaline, however
, has moved out from its original host rock into tourmaline-rich pegma
titic veins during regional high-grade metamorphism, and into very lat
e tourmaline-quartz joint fillings during post-tectonic block movement
. Since the anomalous concentrations of tourmaline occur both in parts
of the footwall rocks as well as in the exhalative, ore-bearing zone,
this type of alteration is likely to be part of the productive hydrot
hermal system. In contrast, calc-silicate alteration, occurring in def
ormed veinlets and flattened network veins is probably of later, syn-m
etamorphic origin. The primary driving force behind the circulation of
the hydrothermal fluids is presumably the high geothermal gradient, a
s suggested for so many other sediment-hosted exhalative zinc-lead dep
osits. A combination of the macroscopically identifiable local alterat
ions, that left their traces as now secondary infillings with tourmali
ne and calc-silicates, should rouse enough suspicion for the presence
of a Zinkgruvan-type deposit. Once the target areas have been identifi
ed, the sulphide mineralizations can be traced by following the uneven
ly distributed geochemical anomalies: very high K2O contents (> 9 wt %
), B, Ba, CaO, MnO, TiO2 and Cs for the Zinkgruvan-type of ores, and F
e2O3 + MgO, Ce and Cs for the Lovdalen-type of sulphide mineralization
related to ferro-magnesian alteration.