SYNTHESIS OF A NEW ASYMMETRIC CYCLOPENTADIENYL LIGAND - APPLICATION TO THE PREPARATION OF A TRIVALENT SAMARIUM COMPLEX

Authors
VANDEWEGHE P BIED C COLLINS J MARCALO J SANTOS I
Citation
P. Vandeweghe et al., SYNTHESIS OF A NEW ASYMMETRIC CYCLOPENTADIENYL LIGAND - APPLICATION TO THE PREPARATION OF A TRIVALENT SAMARIUM COMPLEX, Journal of organometallic chemistry, 475(1-2), 1994, pp. 121-126
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
475
Issue
1-2
Year of publication
1994
Pages
121 - 126
Database
ISI
SICI code
0022-328X(1994)475:1-2<121:SOANAC>2.0.ZU;2-7
Abstract
A short synthesis of a new asymmetric cyclopentadienyl ligand 2 (Cp'H) substituted by a benzyl ether group in the beta position on the side chain of the ring is described. Reaction of its potassium salt with sa marium triiodide leads to the isolation of a trivalent samarium comple x Cp'2SmI.