REACTION OF 2,4-DITHIO-1-TUNGSTABICYCLO[1 .1.0]BUTANE-BIS-TETRAFLUOROBORATE COMPLEXES WITH THIOUREA

Authors
SCHUTT W OSTERMEIER J ORAMA O KREISSL FR
Citation
W. Schutt et al., REACTION OF 2,4-DITHIO-1-TUNGSTABICYCLO[1 .1.0]BUTANE-BIS-TETRAFLUOROBORATE COMPLEXES WITH THIOUREA, Journal of organometallic chemistry, 475(1-2), 1994, pp. 177-181
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
475
Issue
1-2
Year of publication
1994
Pages
177 - 181
Database
ISI
SICI code
0022-328X(1994)475:1-2<177:RO2.>2.0.ZU;2-2
Abstract
The reacting of dicationic 1-tungsta-2,4-dithiabicyclobutane complexes (1a,b) with thiourea dealkylation gives monocationic, bicyclic comple xes in high yields. Further attempts to eliminate the remaining second S-methyl substituent by use of stronger bases in order to obtain the corresponding dithiocarboxylato complexes failed so far.